The History of Chemistry
Chemistry is everywhere, and involves everything. But how did chemistry get to be what it is? I'm Steve Cohen, a chemist and writer, bringing you The History of Chemistry. This podcast explores the development of chemistry from prehistoric times to the present, including the people and societies who made chemistry what it is today. The History of Chemistry is for you, whether you hated chemistry in high school, or got a PhD in inorganic chemistry. We'll explore how chemistry affected art, music, language, politics and vice-versa. Whether it's ancient Greek philosophers, medieval alchemists, or modern laboratory apparatus, it's all here. Don't forget to support my series at https://www.patreon.com/thehistoryofchemistry !
Episodes
184: Alles ist Chemie (Conclusion)
I conclude this series, touching on why I ran this podcast. I give eleven overarching goals for the podcast. I also go far back into my own past, and an event which eventually led to me speaking to you about chemistry. Finally I send you off with an announcement about a national award I will accept in 2026. Please continue to support this podcast, because it costs money to keep this series posted
183: New World Coming
I give a brief history of finding planets around other stars, including discovery by gravitational wobbling, dimming as the planet crosses in front of its star, and even seeing an actual planetary image by blocking the star's glare. I discuss what sort of spectroscopic signals might be present for life in a planet's atmosphere. Finally I offer some planets already detected whose temperat
182: It's Life, Jim, But Not As We Know It
We take an imaginary trip around our Solar System to hear the history of chemical attempts to find life, starting in the late 1950s. Among our stops on the tour include Venus, Mars, Europa, and Titan. Included in the tour are temperature measurements, spectroscopic views, gas chromatography, radioactive labeling, photographs, electrical conductivity, and more.Support the showSupport my podcast at
181: A Work in Progress
In which we bring research into molecular machines up to date. We discuss fuels, specifically what chemists think are the best kinds of fuels to power these little molecules. We discuss what makes a molecular machine different from a regular-sized machine. We also talk about molecular machines as a subset of "molecular devices." Finally, we mention a poll for researchers that IUPAC has s
180: Farm to Market
Instead of just digging in the ground to extract minerals, over the past half-century scientists have begun to explore agriculture of hyperaccumulating plants to pull elements--including heavy metals--out of the topsoil. We explore the recent history of this topic, its advantages and pitfalls.Support the showSupport my podcast at https://www.patreon.com/thehistoryofchemistryTell me how your life r
179: This Episode is Meta
The History of Chemistry is itself an academic discipline, and in this episode we explore the history of chemical history. We start with chemist Thomas Thomson, and work our way forward in time, through the various books on the subject, the founding of the History of Chemistry Section of the American Chemical Society, various chemical-history journals, the Science History Institute, and the Royal
178: Honors and Awards
In which we explore the various honors and awards available to chemists, starting in high school with the International Chemistry Olympiad, founded during the Cold War; college with Phi Lambda Upsilon; and a variety of awards given to chemists during their professional careers by different chemical societies.Support the showSupport my podcast at https://www.patreon.com/thehistoryofchemistryTell me
177: Greek Salad
In this episode we run through the Greek alphabet and see the history behind each symbol as used in chemistry, from alpha for alpha particles to omega as in omega-fatty acids. We encounter a couple of Greek letters not used as chemical symbols too.Support the showSupport my podcast at https://www.patreon.com/thehistoryofchemistryTell me how your life relates to chemistry! E-mail me at steve@histor
176: Inside Information
While outdoor solar cells make big news, there is a quiet revolution also for solar cells that make do with far less illumination, indoor lighting. We discuss requirements for such photovoltaic cells, matching their sensitivity to various kinds of indoor lamps, and such developments in the last couple of decades. We discuss research into various materials for these low-light panels. Finally, we sh
175: It's All Fun and Games Until...
Chemistry can be fun, too, so we explore some of historical satirical art about chemistry, humor based on nonsensical molecular structures, actual compounds with funny chemical names, and even compounds with humorous molecular structures. We discuss chemistry-related parody songs, plus a bonus of me singing an actual song from 1901. We hear of some chemistry games designed to teach students. From
174: Just Add Water
Water, the most important chemical for us, deserves its own episode describing the history of how chemists understand it. We start with pre-Enlightenment views of water as an element, then as a compound, then how electricity affected our understanding, then with dissolved salts, the crystal structure of ice, water's actual molecular structure, and how hydrogen bonding affects it.Support the s
173: Midnight Blue
We start with a 1927 patent awarded to George Washington Carver, an agricultural chemist, for a locally-sourced Prussian blue. We learn a bit about Carver's life, education, and hobby of painting which may have led to the patent. We examine the patent in some detail, and then hear how it's been revived by a modern artist. Then we discuss other blue pigments throughout history, ending wit
172: A Life of Its Own
In which we discuss the history of scientists attempting to determine a half-life of a specific radioactive isotope of samarium, and why that determination is so important for other branches of science. We learn of the poor quality of the observation, how at least one result was retracted, and how a new way to measure half-lives offers hope for a resolution to this problem.Support the showSupport
171: Talk Dirty to Me
This is a brief history of how chemists understand the way liquids wet things. The first glimpse was by Francis Hauksbee in the early 1700s, and how water rises in narrow tubes. Through the 18th century, natural philosophers described surface tension. The 19th century brought understanding of wetting via macroscopic observations and descriptions. The 20th century added insights of quantum mechanic
170: A Clean Break
In which we talk about the history of fractals and how they relate to chemistry. There is a brief overview of what a fractal is and how it developed in mathematics. Then we talk of how fractals apply to chemistry, including surface reactions, descriptions of molecular structures both artificial and natural, growth of polymers, and even how the concentrations and flows of minerals in streams follow
169: A Bone to Pick
It's an ancient story, but fossils have been with us since time immemorial. In this episode, we hear about the history of chemists and their interpretation of fossils. Scientists first began considering fossils as evidence of past life in the 17th century. We hear about the fossil record, and the oldest fossils, then the oldest fossils with organic matter preserved, and the chemical controver
168: Chill Out
Refrigeration always has been closely intertwined with chemistry. In this episode we explore the history of refrigerants, from the first hints of artificial cooling in the mid-1700s, through the invention of the first practical refrigerator 8 decades later. We talk about a variety of refrigerants through the 20th century. Finally we examine some other newer or less-common methods of cooling.Suppor
167: A Sound Idea
Magnetic tape was an integral part of the new, growing recording industry. Herein we talk about the chemical history of magnetic recording, from the first idea in 1888, onward. We encounter Poulsen, Pfleumer, Stille, Nagai, Mullin, and an array of corporations as well. Finally we discuss a bit about digital computers and the history of magnetic tapes for data.Support the showSupport my podcast at
166: The Dagwood
Here we talk about supersized sandwich compounds and their history, beginning with ferrocene in the 1950s. We go from single-decker to double-, triple, and quadruple-decker sandwich compounds through the 1970s and 1980s, a variety of "breads" and "fillings," and then even bigger as we move to the 21st Century.Support the showSupport my podcast at https://www.patreon.com/thehist
165: Building Blocks
Herein we examine the cubical hydrocarbon, cubane, and its role in chemical history. We talk of difficulties in synthesis, possible uses as an explosive, its use as an isostere to benzene in medicinal compounds, and polymers of cubane. Patreon supporters can download a supplemental sheet to see some of the molecular structures I discuss.Support the showSupport my podcast at https://www.patreon.com
164: Mirror, Mirror
In which we talk about how chirality, or handedness, has diffused through chemistry since its discovery in the 19th century, starting with Louis Pasteur. We look at work by Arnaldo Piutti and Emile Fischer. We discuss not only organic compounds, but amino acids, proteins, DNA, and inorganic chiral compounds. Ultimately we have to bring up the question of the biochemical handedness of life. Patreon
163: Basic Fuel
In which we talk about the history of using ammonia, the nitrogen analog of methane, as a fuel. We start two centuries ago with Goldsworthy Gurney, move to the mid-19th century when horseless carriages began to appear in Europe. World War II spurred necessary fuel adjustments to public transportation. We then examine post-war research. We tackle some pros and cons of using ammonia as fuel, as well
162: The Game of Life
Here we talk about how chemists historically have viewed the way life began: as chemicals self-organizing. The earliest serious chemical views began in the 1870s, with synthesis of proteins. Ideas through the decades included warm ponds, auto-catalytic enzymes, genes (whatever they were), a primitive reducing atmosphere, lightning bolts, and DNA or RNA.Support the showSupport my podcast at https:/
161: Political Science
Contrary to popular belief, chemists have always found involvement in politics. Herein are some examples of chemists getting involved politically, whether willingly or unwillingly, from the past 250 years, starting with Englishman Joseph Priestley.Support the showSupport my podcast at https://www.patreon.com/thehistoryofchemistryTell me how your life relates to chemistry! E-mail me at steve@histor
160: Reuse It or Lose It
We look at the history of some recent problems in recycling materials. First we examine the history of wind farms, and how to recycle the fan blades. Second we talk about recent history and problems of recycling polyethylene terephthalate. Then we discuss the persistent and growing problem of electronics waste. Finally, we briefly touch on recycling of spent batteries.Support the showSupport my po
159: Suck It Up, Buttercup!
Given the environmental catastrophe into which we now zombie-walk, here is a bit about the history of extracting greenhouse gases directly from the air. Extracting carbon dioxide from the atmosphere began in the 1930s, but proposals to do it environmentally only began about 25 years ago, with the first large-scale systems appearing in the 2020s. We also talk a little about pulling a worse gas, met
158: It's a Gas
We hear about the history of hydrogen gas as a fuel, starting in the early 1800s with François Isaac de Rivaz. We continue through the 19th and 20th centuries, with dual-burning vehicles, airplanes, and fuel-cells. We talk of advantages and disadvantages of such engines, and the ecological spectrum of hydrogen gas.Support the showSupport my podcast at https://www.patreon.com/thehistoryofchemistryT
157: Cain and Abel
In which we talk about the history of differently abled chemists, from around the year 1600 to the present. We mention some differently abled chemists, and how the American Chemical Society and Royal Society of Chemistry handle things, plus hope for continued improvement in the future.Support the showSupport my podcast at https://www.patreon.com/thehistoryofchemistryTell me how your life relates t
156: Quantum Love
We hear about the recent history of quantum computing to do quantum calculations on molecules. First we briefly discuss different types of computers. Then we talk about the kinds of calculations chemists want to do with quantum computers. We also learn about some ways chemists currently use to simplify the mathematics for quantum calculations.Support the showSupport my podcast at https://www.patre
155: Sci-fi Chemistry
In which we [cue theremin!] discuss how chemistry is presented in science-fiction stories. We start with Mary Shelley's "Frankenstein," move through Jules Verne and H.G. Wells, then to 20th-century writers like Isaac Asimov. Kurt Vonnegut, Fred Hoyle, H. Beam Piper, and many others. We talk of "Star Trek," "Battlestar Galactica," and David Foster Wallace.Support
154: Tile by Tile
We discuss the history of finding quasicrystals, those arrays of atoms that are like crystals--but aren't quite crystals. These are rarely talked about in undergraduate classes. We start with a purely mathematical question by David Hilbert, and move forward through the 1960s and 1970s, till actual quasicrystals were discovered in the 1980s. Then we reach the point where natural quasicrystals
153: Plastic Arts
We finally return to polymers, but in a more ecological way. We learn about using wood waste to make plastics. We hear of how to make plastic naturally degrade in the environment, whether with bacteria, sunlight, zapping it with ions, or heating up without oxygen. We also learn of new methods to mine plastics for hydrogen as fuel.Support the showSupport my podcast at https://www.patreon.com/thehis
152: Built to Last
We give a "solid foundation" to chemistry by recounting the history of concrete, starting with the earliest architectural use of lime around 10,000 years ago. We continue through ancient history and modern times with Roman concrete, the loss of its recipe, and (partial) rediscovery in the Renaissance. We continue to the present and the likely complete rediscovery of Roman concrete in the
151: No Bones about It
This episode relates the history of the new field of "skeletal editing" of molecules. While there have been a few known reactions of this type since the very late 1800s, the general system was unknown till the 21st century, beginning with Marcos Suero. We add to the mix Mark Levin and Guangbin Dong, talk of what precisely this type of chemistry does, and relate the wish-list of chemists
150: The Medium is the Message
We reach the Big 1-5-0, in which I discuss the venerable history of mRNA vaccines, from the 1960s to the present, from a chemical point of view. We hear of transferring mRNA into cells, then transferring anti-viral mRNA into cells. There are a variety of mRNA vaccines under study--not merely COVID, but flu, RSV, and even cancer treatments. Patreon supporters may download a supplemental sheet with
149: It's the Kosher Thing
In this episode we touch on how chemistry has directly influenced religion. Our example is how knowledge of chemistry affected a rabbi's decision to allow a certain brand of carbonated beverage to claim that it is kosher, that is, fit to be ingested by Jews who follow traditional Jewish laws and customs regarding food.Support the showSupport my podcast at https://www.patreon.com/thehistoryofc
148: The New Electronics
What if we could make flexible electronics for clothing or medical sensors? We examine the history of this quest from the 1990s onward, focusing on liquid-metal electronics. We explore what that means, the pros and cons, and how it might work. Then we talk about creating electronic components using wood (really!), which began in the 2010s, ranging from wooden batteries to wooden transistors.Suppor
147: Good to the Last Drop
The history of chemistry in water microdroplets is discussed. We start with the observation by R. Graham Cooks that certain chemical reactions went faster inside ultra-small droplets of liquid relative to beaker-sized amounts. We examine the years-long arguments between Dick Zare and Himanshu Mishra over peroxide formation in microdroplets. We talk a bit about some reasons why reactions may go dif
146: Electrical Switch
In this episode we examine the history of non-lithium batteries. We talk of changing the anode material and cathode material, whether separately or together. This involves changing the graphite anode to silicon, changing to sulfur anodes, air-based cathodes, different solvent molecules to assist transport of lithium ions, and even calcium batteries. Finally we discuss the flow battery, invented wa
145: State of the Art
In which we learn about the beginnings of chemistry applied to art conservation, from the initial attempts by Edward Forbes, but especially when he hired Rutherford John Gettens. We discuss Harvard University's Pigment Collection, plus various analytical tools chemists use to examine art, both light-based and non-light-based. We talk of several institutions with strong chemical applications f
Break Time
Dear Listener,I have been posting episodes weekly for two and a half years. I need a short break. I promise I will be back very soon. I have many more episodes already written and recorded for you. Please stay tuned. Until then….brave the elements!Support the showSupport my podcast at https://www.patreon.com/thehistoryofchemistryTell me how your life relates to chemistry! E-mail me at steve@histor
144: Rare as Hens' Teeth
Here we explore the history of unusual and uncommon isotopes of known elements on the periodic table. We discuss the (almost) true statement that all isotopes of an element react the same. Then we reach inside the atomic nucleus and hear of theories to describe nuclear structure and--hence--stability of various isotopes, beginning with Dmitri Ivanenko's work. We learn of the best model, shell
143: Queer as a Clockwork Orange
In which I give a brief history of queer chemists. We talk of the rise of queer scientific associations, and the slog to acceptance of the Gay and Transgender Chemists and their Allies in the American Chemical Society, some current queer chemists around the world, and something of the challenge of queer chemists in the Britain.Support the showSupport my podcast at https://www.patreon.com/thehistor
142: Molecular Valves
Science-fiction writers (and scientists) have been promoting molecular transistors since the 1950s, and we explore the history of why that hasn't happened yet. We start with the parallel sci-fi writer (and biochemist) Isaac Asimov's "molecular valves" and physicist Arthur von Hippel's "molecular engineering." We talk of military projects that failed, and theoreti
141: Chemical Communications
In this episode, I have a conversation with Professor David Perlmutter in the Communications Department at Texas Tech University, on the public's impressions of chemistry, and what value chemistry brings to the wider world.Support the showSupport my podcast at https://www.patreon.com/thehistoryofchemistryTell me how your life relates to chemistry! E-mail me at steve@historyofchem.comGet my bo
140: Chemical Paranoia
We start with the first chemical conspiracy theory from 1996, "chemtrails." Then we move to another popular chemical hoax, "alkaline water" somehow being healthy for you. Related to that are the bizarre "hexagonal water" and water memory ideas. Other creative pseudochemical hoaxes are denial of global warming and the gasoline pill, creating fuel from non-fuel with mer
139: To the Max
A new material, the MXene, discovered in 2010, is the topic of this episode. We hear of its creation and derivation at Drexel University in Philadelphia. Then we learn of ways to create single layers, variations in materials, and new methods of synthesis of MXenes. Finally, we discuss the practical uses of MXenes.Support the showSupport my podcast at https://www.patreon.com/thehistoryofchemistryTe
138: Smells Like Teen Spirit
We finally get to discuss what the term "aromatic compound" means in chemistry, from Michael Faraday's report in 1825 of a new organic compound (we call it benzene), to von Hofmann's first use in 1856 (without defining it) of the term "aromatic". We examine the ensuing controversies and definitions of "aromatic compound," how people modeled molecularly and d
137: Light My Fire
Aerogels, those feather-weight materials, have a century-old history. We begin with Samuel Kistler, the inventor of the first aerogels, and move forward through time with loss of interest in them, then revival of interest in the 1970s. We learn about gradual improvements in their fabrication over time. Then we talk of their fascinating properties, and then their uses.Support the showSupport my pod
136: AI, Robot
Artificial intelligence, or AI, can be applied to chemistry, too. Here we discuss a brief history of AI, especially for chemistry, beginning with Djerassi's DENDRAL program. We talk of the current problems in chemistry to which AI is being applied over the last couple of decades. We also examine what is not doable (yet) in chemistry with AI.Support the showSupport my podcast at https://www.pa
135: Bond, Chemical Bond
In which we consider what, really, is a chemical bond. Lewis and Langmuir promoted the idea that bonding was sharing of electron pairs. Then we hear about Slater, Hellman, and Ruedenberg's discussion of how covalent bonding works. Kossel and Lewis also introduced ionic bonding. Finally Drude and Lorentz offered metallic bonding. But there are more chemical bonds: the hydrogen bond, the haloge
134: Atto-boy!
In which we talk about the fastest spectroscopy yet, attosecond spectroscopy, which can resolve electrons moving around atoms. The topic begins with Christian Spielmann in 1997, working to get shorter and shorter laser pulses, and continues with Ferenc Krausz. We discuss what you might be able to inspect using these short light pulses, such as how the shape of atomic orbitals oscillates after ioni
133: A Horse of a Different Color
Instead of molecules that absorb light based on their molecular orbitals, this episode talks of nanostructures and their materials that refract light based on interference of light waves. We start with Robert Hooke who described this process in his book Micrographia. We continue through Isaac Newton and Lord Rayleigh. We discuss Eli Yablonovitch's photonic crystals. We mention various kinds o
132: Name Dropping
This episode concerns the phenomenon in organic chemistry of classifying a set of similar reactions by a single umbrella name. Most named reactions honor a person, but not always. We discuss the early history of named reactions from the 1870s onward. We then talk about the slant of named reactions towards white men, and away from other people, and even whether that can be a problem for minority an
131: From Fluor to Ceiling
Polyfluoroalkyl substances, or PFAS, seem to be ubiquitous now in the environment and the news. In this episode I delve into why chemists found these compounds so fascinating and useful. Then I discuss some history of how the world finally learned how dangerous these compounds can be if used and disposed of improperly. Finally I talk of some possible methods chemists are currently researching on h
130: I Have an Axe to Grind
Mechanochemistry, using purely mechanical processes to run a reaction, is much less known in the chemical world, but has been around since the ancient Greek Theophrastus described a mechanochemical process. We describe the history of mechanochemistry from then through its rediscovery by Michael Faraday, and the first systematic attempts to understand it by Mathew Carey Lea. He got into a dispute w
129: Sheets and Giggles
In which we learn of the history of graphite, its molecular structure, and electrical properties. Then we discuss the isolation of thinner and thinner layers of graphite through the mid-to-late 20th century. The first isolation of a single atomic layer of graphite, called graphene, was accomplished in 2004 by Andre Geim and Konstantin Novoselov, which set off a new flurry of chemical research, muc
128: Heavy, Man, Heavy!
With this episode, we complete our history of the discovery of the elements (up through writing this episode). We talk of elements 110 through 118, completing that row of the Periodic Table, and the various experiments that the major heavy-ion research facilities in Russia, Germany, the USA, and Japan, were doing. We begin to hear of collaboration between several groups as the difficulties of obta
127: Black is Beautiful
In which we discuss the entry of People of Color into chemistry, mostly in the USA. We start with the first Black to get an Ph.D. in Chemistry in the USA, St. Elmo Brady, and work forward through the 1940s through the 1960s. We discuss various organizations to assist people of color in chemistry (and other sciences), such as NOBCChE, SACNAS, AISES, and the Society for Asian Scientists and Engineer
126: Run of the Mill
In which we talk of a huge problem currently plaguing chemistry (and science in general), the "paper mill," in which researchers pay to get their name attached to others' publications, or they write fraudulent publications and pay to get them in print. We hear of a Chinese firm discovered to be such a broker, possible reasons why chemists would fake research, and specific examples o
125: Das Model
Here we discuss all sorts of kits chemists use to build models of different molecules. We start with the pre-molecule set built for John Dalton, and then we hear of August von Hofmann's set for lecture demonstrations. We talk of John Dewar's brass constructions, and then to Tinkertoy-like setups in the 20th century. Plastic first appears in molecular-model kits by the 1950s, and we conti
124: Lumen Large
Our history of LEDs continues with the entry of LEDs into commercial lighting. We talk of different ways to get white light out of LEDs, and materials for white-light LEDs. We briefly discuss color temperature because there are different kinds of white. Then we hear of the publication of an article in 2000 that consolidated thinking about home usage for LEDs, and why LEDs have advantages over othe
123: Setting the Ground Rules
This episode gives a basic review of geochemistry, starting with pioneers such as Christian Friedrich Schönbein, Frank Wigglesworth Clarke, and thence into the 20th century, especially Victor Goldschmidt. We hear about the development of geochemical societies around the world, then we talk about various subfields of geochemistry. The question of "what's inside the Earth" is still a
122: Catch the 'Wave
Even though the potential for using microwaves to do chemistry was there since 1946, it wasn't until the late 1970s that the first use of microwaves in the chemistry laboratory appeared. This episode covers the development of microwave chemistry from moisture analyzers to significant study of reactions, and then finally laboratory-standard microwave ovens appeared. We mention the controversy
121: Let the Sun Shine in
We talk about perovskite minerals and compounds, their discovery, and general crystal structure. Then we learn about how researchers gradually learned about their interesting electrical and optical properties. We hear of Tsutomu Miyasaka’s paper about building a solar cell using these perovskite minerals, and the sudden interest in making commercial, practical solar cells from perovskites. We delv
120: Snap Judgement
Click Chemistry came about as several researchers came to similar conclusions in parallel, but from different angles: Barry Sharpless, Morten Meldahl, and Carolyn Bertozzi. We hear about their research goals in the 1990s and early 2000s: to snap together smaller molecules in a reliable way, perhaps with pharmaceutical or biological experiments and results in mind. We learn of Sharpless's goal
119: Tiny but Mighty
We reach the point in our chemical history when microplastics were first recognized as a pervasive environmental pollutant. Visible plastic bits were first found by Edward Carpenter and K.L. Smith in the ocean back in 1972, and such detritus was confirmed all over the world's oceans over the next decades, resulting in the name "Eastern Garbage Patch" by 1997. Yet only in 2004 did Ri
118: Hold Tight, Stick Tight
This episode deals with glues and adhesives, from prehistoric times to the present. We talk of prehistoric glue from tree saps, petroleum tar, animal glues, casein glues, albumin glues, and starch glues, all known in ancient times. Medieval knowledge added fish glue, and by the Renaissance we start industrial-scale adhesive factories. The 19th century brought rubber cement, mucilage, and library p
117: The Set Table
The Periodic Table we've all seen in chemistry books and classes is not always the way it was, nor the way it must always be. In this episode we explore all kinds of periodic representations of the properties of elements, from Mendeleev's first published table in 1869, through wide and narrow tables, and spirals. There are even three-dimensional "tables," from helices to submar
116: Open Frame of Mind
We introduce the first chemical construction set in chemistry (besides natural proteins, starches, sugars, etc.), the metal-organic framework. A DuPont employee, E.A. Tomic, invented this type of molecule in the 1960s, but it took until Omar Yaghi's research in 1990s until chemists realized the value of metal-organic frameworks. We discuss the experiments and results leading up to Yaghi'
115: Reach for the Stars
In this episode we talk about astrochemistry, which began in the 20th century. The first detection of molecules outside our solar system began with Theodore Dunham, which was finally recognized as a molecule in 1940. We talk of Gerhard Herzberg, Polydore Swings, and Dirk ter Haar, then meet Lyman Spitzer. Radio astronomy then became important in the 1960s and 1970s, allowing astrochemists to ident
114: We Can Work It Out
Here we talk of the first real molecular machines of the 1990s, and the chemistry advances required to invent them. We define what such a machine is, and reach back into organic chemistry of the 1940s and 1950s for "conformational analysis." We recall the Bell Labs chemists Harry Frisch and Edel Wasserman, and their foundation of chemical topology. Gottfried Schill, Arthur Lüttringhaus,
113: Ready Set Go
On a topic that's a little different, here is an episode about chemistry sets. We explore their origins in Germany as portable laboratories in the late 1600s. Johann Fredrich August Göttling's portable laboratory might be considered the first true chemistry set as an amusement rather than solely a carry-along lab. Our story continues in Britain through the 19th century, and then in the U
112: Connect the Dots
Here we discuss the discovery of quantum dots, those small particles hovering between molecule-size and macroscopic-size. We begin with physicist and refugee from Nazis Herbert Fröhlich, whose predictions led the way in the 1930s. Among the researchers we encounter are Aleksei Yekimov, Louis Brus, and Moungi Bawendi. Quantum dots were real, but could they be made reliably of specific sizes? The an
111: O Say Can You See
We return to the history of light-emitting diodes, LEDs, but now talk about the development of organic versions, OLEDs, from the secret work of Roger Partridge to the now classic publication by Ching Tang and Steven Vanslyke at Eastman Kodak. Through the 1990s, more and more colors were added, so by the mid-1990s, the first commercial OLED product was marketed by electronics firm Pioneer. We also
110: Rattle My Cage
After chemists discovered the soccer-ball molecule, buckminsterfullerene, and its siblings--could they do chemistry with it? We explore putting atoms and small molecules inside the ball. Then we discuss attaching atoms and molecules on the outside of the cage itself. We talk of futuristic uses for fullerene chemistry. We even mention sliding fullerenes inside a single-wall carbon nanotube.Support
109: Bon Appetit
This episode deals with the field of molecular gastronomy, founded in the late 1980s and grew in the 1990s, under the leadership of Nicholas Kurti and Hervé This. We explore what molecular gastronomy researches and promotes, its goals, but also its controversies.Support the showSupport my podcast at https://www.patreon.com/thehistoryofchemistryTell me how your life relates to chemistry! E-mail me
108: Fuel Transformation
In which I discuss my Dear Wife's doctoral dissertation, which deals with converting hydrocarbon fuel (say, methane) into a liquid (say, methanol) for much easier transportation from source to need. We dig into many details of experimentation, laboratory equipment, and even an unexpected side reaction. This was and is a popular topic among organometallic chemists since the 1980s.Support the s
107: Transfermium Wars
We now look at the controversies over discovery and rights to naming elements 104 to 109 in the 1960s to 1990s. The various laboratories included University of California--Berkeley, JINR at Dubna, and GSI Helmholtz Centre for Heavy Ion Research in Darmstadt. There were arguments and spats over who discovered what, and what constitutes discovery. Eventually a Transfermium Working Group of the Inter
106: Natural Order of Things
Through the 1960s up to the 1990s scientists learned how to read DNA's sequence of bases, first by handfuls, then faster and faster. Ray Wu learned to determine the order of a dozen or so bases in the late 1960s. The mid-70's brought Fred Sanger and Alan Coulson's "plus and minus" method, and the first viral DNA sequenced. We then talk of Maxam and Gilbert's method, K
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